I personally find it weird that you shouldn't be able to do it. I have a friend that bought the tickets online and printed the tickets at the La Caixa terminal on the match day (he also bought the tickets on the match day though...). I haven't used the option personally though, so I would probably ask them to be 100% sure. Did you buy through the official website? If so, then why didn't you pick the "Print at home" option? If you have any other questions about the city or the game, then please ask.
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